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  2. Le Chatelier's principle - Wikipedia

    en.wikipedia.org/wiki/Le_Chatelier's_principle

    Le Chatelier's principle (pronounced UK: / lə ʃæˈtɛljeɪ / or US: / ˈʃɑːtəljeɪ / ), also called Chatelier's principle (or the Equilibrium Law ), [1] [2] is a principle of chemistry used to predict the effect of a change in conditions on chemical equilibrium. [3] The principle is named after French chemist Henry Louis Le Chatelier ...

  3. Principle of minimum energy - Wikipedia

    en.wikipedia.org/wiki/Principle_of_minimum_energy

    The principle of minimum energy can be generalized to apply to constraints other than fixed entropy. For other constraints, other state functions with dimensions of energy will be minimized. These state functions are known as thermodynamic potentials. Thermodynamic potentials are at first glance just simple algebraic combinations of the energy ...

  4. Energy minimization - Wikipedia

    en.wikipedia.org/wiki/Energy_minimization

    Energy minimization. In the field of computational chemistry, energy minimization (also called energy optimization, geometry minimization, or geometry optimization) is the process of finding an arrangement in space of a collection of atoms where, according to some computational model of chemical bonding, the net inter-atomic force on each atom ...

  5. Steric effects - Wikipedia

    en.wikipedia.org/wiki/Steric_effects

    In organic chemistry, steric effects are nearly universal and affect the rates and activation energies of most chemical reactions to varying degrees. In biochemistry, steric effects are often exploited in naturally occurring molecules such as enzymes , where the catalytic site may be buried within a large protein structure.

  6. Principle of maximum entropy - Wikipedia

    en.wikipedia.org/wiki/Principle_of_maximum_entropy

    e. The principle of maximum entropy states that the probability distribution which best represents the current state of knowledge about a system is the one with largest entropy, in the context of precisely stated prior data (such as a proposition that expresses testable information ). Another way of stating this: Take precisely stated prior ...

  7. Lagrangian mechanics - Wikipedia

    en.wikipedia.org/wiki/Lagrangian_mechanics

    The stationary action principle requires that the action functional of the system derived from L must remain at a stationary point (a maximum, minimum, or saddle) throughout the time evolution of the system. This constraint allows the calculation of the equations of motion of the system using Lagrange's equations. [4]

  8. Project management triangle - Wikipedia

    en.wikipedia.org/wiki/Project_management_triangle

    Project management triangle. The project management triangle (called also the triple constraint, iron triangle and project triangle) is a model of the constraints of project management. While its origins are unclear, it has been used since at least the 1950s. [1] It contends that:

  9. Lagrange multiplier - Wikipedia

    en.wikipedia.org/wiki/Lagrange_multiplier

    Lagrange multiplier. In mathematical optimization, the method of Lagrange multipliers is a strategy for finding the local maxima and minima of a function subject to equation constraints (i.e., subject to the condition that one or more equations have to be satisfied exactly by the chosen values of the variables ). [1]