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Peroxide. In chemistry, peroxides are a group of compounds with the structure R−O−O−R, where the R's represent a radical (a portion of a complete molecule; not necessarily a free radical [1]) and O's are single oxygen atoms. [2] [3] Oxygen atoms are joined to each other and to adjacent elements through single covalent bonds, denoted by ...
Hydrogen peroxide ( H2O2) is a nonplanar molecule with (twisted) C 2 symmetry; this was first shown by Paul-Antoine Giguère in 1950 using infrared spectroscopy. [9] [10] Although the O−O bond is a single bond, the molecule has a relatively high rotational barrier of 386 cm −1 (4.62 kJ / mol) for rotation between enantiomers via the trans ...
Acetone peroxide ( / æsəˈtəʊn pɛrˈɒksaɪd / ⓘ also called APEX and mother of Satan [3] [4]) is an organic peroxide and a primary explosive. It is produced by the reaction of acetone and hydrogen peroxide to yield a mixture of linear monomer and cyclic dimer, trimer, and tetramer forms. The monomer is dimethyldioxirane.
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Hydroperoxide. Hydroperoxides or peroxols are compounds of the form ROOH, where R stands for any group, typically organic, which contain the hydroperoxy functional group ( −OOH ). Hydroperoxide also refers to the hydroperoxide anion ( −OOH) and its salts, and the neutral hydroperoxyl radical (•OOH) consist of an unbond hydroperoxy group ...
Main group peroxides are peroxide derivatives of the main group elements. Many compounds of the main group elements form peroxides, and a few are of commercial significance. Examples. With thousands of tons/year being produced annually, the peroxydisulfates, S 2 O 2− 8, are preeminent members of this class.
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The peroxide value is defined as the amount of peroxide oxygen per 1 kilogram of fat or oil. Traditionally this was expressed in units of milliequivalents, although in SI units the appropriate option would be in millimoles per kilogram (N.B. 1 milliequivalents = 0.5 millimole; because 1 mEq of O2 =1 mmol/2=0.5 mmol of O2, where 2 is valence).